ABSTRACT Covered lagoon biodigesters are widely used in Brazil for treatment of agro-industrial effluents; however, under natural conditions, they operate at temperatures below the ideal. Thus, external sources for heating the effluent can enhance reactor performance and optimize thermal exchanges between the biodigester and the environment. This study aimed to evaluate the thermal exchanges in the internal and external environments of a covered lagoon biodigester from the influence of effluent heating through solar energy. Mathematical modeling (EnergyPlus software) was used as a tool to simulate thermal exchanges and obtain heat transfer rates. To do so, two scenarios were considered: with and without heated effluent. The results showed that solar radiation is the primary source of heating for anaerobic reactors and that the high thermal inertia of the soil contributes to a small variation in temperature of the resident biomass over the course of the day, even in the scenario with heated effluent. The temperature of the resident biomass reached and stabilized at 30°C, even after thermal exchanges with biogas and soil, in both hot and cold periods when heating was applied.

ABSTRACT Anaerobic digestion (AD) stands out as a degradation pathway for the treatment of agro-industrial waste. This study aimed to evaluate the biogas production (Pb) from the co-digestion of swine (SW) and laying hen waste (LHW) under different temperature conditions (psychrophilic x mesophilic). The studies were carried out on a laboratory scale in anaerobic reactors (1.25 L) in a batch system for 60 days. Three mixtures in volumetric proportions (%) of 25/75 (P1), 50/50 (P2), and 75/25 (P3) (SW/LHW) were studied. The mixtures were characterized before and after AD in terms of TS, VS, and COD under temperatures of 18 and 36 °C, with Pb measured daily. Pb was higher at 36 °C for all mixtures compared to the psychrophilic condition (18 °C). Among the mixtures, the highest Pb value was observed for P3, reaching 0.34 and 0.60 m3 biogas kg−1 CODremoved for 18 and 36 °C, respectively. The digestate showed an increase in the contents of micro-and macronutrients for P1, P2, and P3 after AD, which indicates its use for agricultural purposes. The co-digestion of swine and laying hen waste is a promising proposal in terms of management and energy recovery of biogas, especially for mesophilic conditions in mixtures with a predominance of laying hen waste.

ABSTRACT Covered lagoon biodigesters (CLB) have been widespread in Brazil in the treatment of pig manure. However, the quantification of biogas production in CLB using mathematical models is still limited and scarce. This study aimed to evaluate and compare six mathematical models—Chen-Hashimoto (Chen, 1983), CETESB (2006), COD Conversion (Chernicharo, 2016), IPCC (2006), Deng (Deng et al., 2014), and modified Stover-Kincannon (Yu et al., 1998)—usually used to estimate methane (CH 4 ), and propose improvements to the models, if necessary. The results were compared with the monitored production (P actual ) in a farm with CLB using the t-test (α = 5%). The Chen-Hashimoto, IPCC, Deng, and modified Stover-Kincannon models showed no statistical difference compared to P actual (405.0 m 3 CH 4 d −1 ), whereas the CETESB and COD Conversion models presented no statistical difference after the proposed improvements. All models can be considered reliable for estimating volumetric methane production after the adaptations, being relevant tools for diagnosis and decision-making regarding the energy recovery of biogas with CLB operation in pig farms.

ABSTRACT Fluorine is released into the water environment naturally or by anthropogenic activities. Fluorine promotes health benefits at low concentrations, but it promotes adverse effects ranging from fluorosis to carcinogenic problems at high concentrations. Although fluorine removal from environment can occur through processes such as adsorption, reverse osmosis, and electrodialysis, the phytoremediation emerges as an accessible and environmentally friendly treatment. This research aimed to study the phytoremediation potential of Landoltia punctata for treating water contaminated with fluorine ion (fluoride). The central composite rotatable design was used to assess the effect of three variables in the process: pH ranging from 5 to 9; phosphate concentration from 0 to 10 mg L−1; and nitrate concentration from 0 to 800 mg L−1. The plants were exposed to a fluoride initial concentration of 5 mg L-1 in 3L-vessels that also included Clark's solution for a period of 10 days. Experimentally, removal of up to 21% was observed for the supplied fluoride. Values of the order of 30% for the removed fluoride mass can be predicted by the obtained model. Landoltia punctata is a promising candidate for the phytoremediation of fluoride-contaminated waters.

ABSTRACT Pig farming stands out as an alternative for decentralized electrical energy production from the use of biogas energy. However, its use is still limited. Thus, this study aimed to estimate and map the biogas production, as well as determine the electric power originated by the use of biogas produced in covered lagoon biodigester from pig farms of different sizes in the state of Minas Gerais, Brazil. The research was based on data provided by the Instituto Mineiro de Agropecuária (IMA). Three forms of electric power were estimated, as follows: (i) total, (ii) current, and (iii) installed. They were estimated from the volume of manure generated at each development stage of the animals. The total electric power corresponded to 31 MW, while the current electric power was equal to 20 MW. The installed electric power was still low and corresponded to 35.4% of the current electric power. The results showed that 55% of the current electric power was concentrated in only two mesoregions (Triângulo Mineiro/Alto Paranaíba and Zona da Mata). Therefore, the use of biogas contributed to providing energy self-sufficiency in pig farms and the generation of decentralized electrical energy.